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Research

Current Research Topics

1. very high efficiency novel solar cells

The world’s annual energy consumption stands at approximately 5x1020 Joules and is predicted to rise to over 7x1020Joules  by the year 2035.  Currently demand is mainly met using fossil fuels (81.2%) while renewable sources account for 12.8 % and nuclear fission 5.8%. With only finite fossil fuel reserves and persistent concerns over nuclear safety, it is a priority to meet as much of the increasing demand as possible with renewable sources.
Of renewable sources sun is by far the most abundant source of energy (more energy from the sun reaching the earth’s atmosphere every 46 minutes than mankind uses in a year). This energy can be converted directly from light to electricity by photovoltaic cells. To date the highest efficiency solar cells have been GaAs based tandem cells, achieving efficiencies of 32% for AM1.5G for un-concentrated radiation and 42.3% for AM1.5D at 406 times concentration. The band gap of a solar cell directly affects the maximum efficiency due to low and high wavelength cut-offs. In 1992 it was discovered that the addition of a small amount of nitrogen to GaAs leads to a large red shift in the materials band gap as well as a decrease in its lattice constant5. This combined with the addition of indium which also decreases the band gap but increases the lattice constant allows the quaternary alloy Ga1-xInxNyAs1-y to have band gaps significantly lower than GaAs but remain lattice matched to it. However, the addition of nitrogen also causes a reduction in the minority carrier mobilities and lifetimes leading to low diffusion lengths making it impossible to produce efficient GaInNAs solar cells using conventional designs. In order to overcome this problem, at Essex we aim to design and study GaInNAs solar cells using two novel approaches. The first is the multiple quantum well (MQW) solar cell design where GaInNAs quantum wells are combined with GaAs solar cells extending the spectral response towards infrared with the aim of improving the current matching in tandem solar cells. The second approach is to use an n-i-p-i doping design which overcomes the problem of low diffusion lengths by consisting of a number of thin n and p type layers connected by selective contacts.

2. Gunn Laser

It is well known that Near Infrared Radiation (NIR) is emitted from propagating high-field domains in a GaAs Gunn device. We have reported the spontaneous emission characteristics from such devices as a function of temperature and electric field. We have also predicted that spontaneous emission may evolve into stimulated-emission in a Gunn device when it is placed in a Fabry-Perot cavity. Indeed the operation of a Fabry-Perot Gunn laser has been demonstrated by us recently at T ≥ 95 K.

The results are analyzed in detail and compared with model calculations.

 

 

The aim of the current work is to study Gunn Vertical Cavity Surface Emitting Laser (VCSEL) which is a truly monopolar device. The principle of the operation is based on the band to band recombination of impact ionized non-equilibrium electron-hole pairs in the propagating high field domains along the Gunn diode, which is biased above the negative differential resistance threshold, and placed in a vertical micro cavity. In conventional Vertical Cavity Surface Emitting Laser (VCSEL) structures, unless specific measures such as the addition of oxide apertures and use of small windows are employed, the lack of uniformity in the density of current injected into the active region can reduce the efficiency and delay the lasing threshold. In a vertical-cavity structured Gunn device, however, the current is uniformly injected into the active region independently of the distributed Bragg reflector (DBR) layers. Therefore, lasing should occur from the entire surface of the device. Furthermore, because the light emission from Gunn domains is an electric field induced effect, the operation of VCSEL are independent of the polarity of the applied voltage defining a surface emitting optical exclusive OR logic gate. Red -NIR VCSELs emitting in the range of 630-850 nm are plausible when Ga1-xAlxAs (x < 0.45) is used the active layer, making them candidates for light sources in plastic fibres (POF) based short-distance data communications.

 

3. Optoelectronics based on InN and In-Rich GaInN

The In1-xGaxN material has the widest range of direct gap of any compound semiconductors extending from 0.7 eV to 3.2 eV which can be utilized in optoelectronic device applications over a wavelength range, from infrared to ultraviolet as shown in the including very many key wavelengths for applications in the medical, environmental and communications fields.

A recent press release by Lawrence Berkeley National Laboratory says of In1-xGaxN: "....It is as if nature designed this material on purpose to match the solar spectrum..... The cost (of solar cells) will be the same order of magnitude as traffic lights.... (They will be) so efficient and so cheap that it could revolutionize the use of solar power

The growth of high quality InN and Indium rich In1-xGaxN have been achieved only recently but an intense research effort has been aimed at understanding the details of the electronic and optical properties of the these alloys.From optoelectronic devices point of view the first commercial target is likely to be multilayer solar cells. In the ternary, In1-xGaxN, a Ga concentration of should produce direct bandgaps between 0.7 and 1.9 eV to match perfectly the useful part of the solar spectrum. Very high efficiencies could be achieved by the use of multilayers with improved radiation hardness over conventional cells. The growth of high quality epilayers of InN (x=0), with intrinsic electron densities of n> 2 10 17 cm-3), mobilities in excess of 2000 cm2 V-1 s-1 implies that InN itself, has immediate potential applications in high power high frequency FETs and terahertz devices for sub-millimeter wave imaging.

Potential applications of the In1-xGaxN Technology

Material                          GaN                                                                                                                                        InN
                      |   (360)       |                |                    |                |                |                |                    |                |   (1610)
Wavelength (nm)         300                            600                                900                         1200                          1500
Technological Applications
Displays/lighting                 370,470,540          640 (violet,     blue, green, red)

Storage                                  405                            650         780 (BD, DVD, CD)
Solar cells                     -----multilayers     profiled in wavelength to solar spectrum with high efficiency-
Communications                          510 (POF)       650     (free-space line-of-sight)                        1300(silica)      1550     (silica)
Pumps                                                         810        980, 1000, 1050                                    14xx, 1480)
                                                                        (YAG,     EDFA, TDFA, PDFA)                                       (Raman, EDFA)
Sensing                                                760                                                                                               1540
                                                                    (Oxygen)-----Many spectroscopic lines------ (ammonia, Methanol)
PDT                      (to match photo-sensitizers for specific     treatment)...
Surgery                            488,532                                                     1064                      1320, 1440
                                          (Argon, YAG     replacement)                            (YAG replacement)
High speed high power FETs        High     carrier density (1014 cm-2) and low effective mass
Terahertz devices                              Due to transient photo-carrier currents, stronger magnitude than any other     semiconductors
 

Acronyms: BD - Blu-ray disc, CD - compact disc,  DVD - digital versatile disc, EDFA - erbium-doped fibre amplifier, PDFA - praseodymium-doped fibre amplifier, 
PDT - photo-dynamic therapy,  POF - plastic optical fibre,  TDFA - thulium-doped fibre amplifier, YAG - Yttrium Aluminum Garnet


4. Optoelectronic devices based on dilute nitrides

III-V Semiconductors are indispensable for today's optoelectronic devices such as semiconductor lasers used in optical communication systems. Likewise, this class of materials is dominant in key high frequency electronics components for wireless communication systems.  The miscibility of binary III-Vs and the possibility to stack such layers of various compositions and doping levels is crucial for all these applications. The tailoring of hetero-structure properties is limited by the different lattice constants of the binary III-Vs, which limit the range of useful compositions and thereby the range of available band gaps. Thus, on the two most commonly used substrate materials, GaAs and InP, the band edges can be tailored to allow only a limited range of useful wavelengths of a maximum of 1200nm for GaAs-based and about 2100nm for InP-based materials. Moreover, the alignment of the band edges, which is highly important for the performance of devices, cannot be tailored by the combination of conventional materials at all.   These limitations encountered in InP and GaAs based devices can be greatly reduced by incorporating a few percent of nitrogen as a group V element into GaAs or InGaAs, i.e. by creating the so-called "dilute nitrides". In dilute nitrides, unlike in all other cases, where a reduction in band-gap energy is achieved by inserting an element that increases the lattice constant, N effectuates this and at the same time reduces the lattice constant. Thus smaller band-gaps can be achieved and the unusual role of N in the lattice also allows a tailoring of band alignments. Both of these effects have opened up a new dimension of band-gap engineering. 

The low loss window of optical fibre has recently been extended to cover 1.3 to 1.7 m m, significantly increasing the potential capacity of optical networks. As a result, optoelectronic devices (such as lasers, detectors, filters and optical amplifiers) operating in this wavelength range dominate photonics research. Many of these devices are enhanced using distributed Bragg reflectors (DBR's) to control the optical field. Typical examples include vertical cavity surface emitting lasers (VCSELs), resonant cavity enhanced (RCE) photodetectors, RCE-LEDs and vertical cavity semiconductor optical amplifiers (VCSOA).

Unfortunately, the device requirements are not met by conventional GaAs or InP based materials, such as InGaAs/GaAs or InGaAsP/InP. Most GaAs-based material systems only allow device operation out to ~1.2  μm, while InP-based systems suffer from poor thermal stability (lowering efficiency) and low refractive index contrast (hindering DBR fabrication). This low index contrast means that many layers are required to achieve high reflectivity InP-based DBRs. Growing thick uniform stacks without defects is very difficult and introduces the additional problem of high series resistance, which retards device dynamics. These problems can be avoided by fusing AlGaAs/AlAs DBRs to the active layers, however, this complicates fabrication, increasing cost and may result in un-reliable devices.

Dilute nitrides avoid many of the problems associated with conventional arsenides and phosphides. Incorporating a few percent of nitrogen into (In)GaAs has a profound influence on its electronic properties. In most III-V materials, substituting an element for one with a smaller atomic radius reduces the lattice constant and increases the bandgap. However, Weyers et.al found that replacing a fraction of arsenic atoms in GaAs with smaller N atoms, rapidly reduces the bandgap. In addition to giving access to smaller bandgaps, nitrogen allows band alignment, lattice constant and strain to be tailored, opening up a new dimension of band engineering.

The quaternary alloy GaInNAs is attractive for a range of devices, offering advantages over conventional narrow gap materials. GaInNAs quantum wells (QWs) can be grown pseudomorphically on GaAs, giving strong carrier confinement (hence thermal stability) and compatibility with GaAs technology, including AlGaAs/AlAs DBRs. GaNAs is less relevant to devices, however, it does allows investigation into the physical properties of dilute nitrides.

                                               (a)                                                                                      (b)

   

Temperature dependence of the PL peak energy (a,) and the FWHM (b) of the modulation doped samples for different nitrogen compositions.

A wide range of novel devices could benefit from dilute nitrides. Devices already demonstrated include VCSEL's, VCSOAs, RCE-photodetectors, RCE-LEDs, multijuction solar cells, modulators and heterojuction bipolar transistors (HBTs). Commercially, the most important devices are for inexpensive optical fiber data transmission at 1300 nm for metro-area links over 10 to 20 km These links are presently considered to be the bottleneck for large-scale optical communications and constitutes a very large market volume. Rapid progress has already led to the demonstration of high quality 1300 nm dilute nitride laser diodes on GaAs and even 1300 nm VCSELs. Emission from dilute nitride devices has even been pushed above 1500 nm, potentially useful for long haul links.

One major difficulty with dilute nitride growth is maintaining good optical quality as nitrogen is incorporated. This has provoked extensive work to establish the factors effecting optical quality, such as composition, growth and annealing conditions. Techniques, such as PL, surface photovoltage spectroscopy (SPS), deep level transient spectroscopy, spectral photoconductivity and STEM, etcare commonly used to investigate the presence of structural and compositional fluctuations, impurities and defects.


                   L-I measurements for the 1600 um SQW laser                                                  Threshold Carrier Density versus temperature

 

In order to analyse and improve the design of functional devices based on dilute nitrides, and further predict the ultra-fast novel devices based on these materials, a through understanding of electron transport, particularly at high electric fields, is necessary. Hot-electron dynamics for longitudinal transport in degenerate 2D GaAs and III-N structures are well documented, where the production of non-equilibrium LO phonons (hot phonons) are well-known to slow down the hot electron energy relaxation.It is also shown that at high electric fields, the randomization of the hot phonon distribution may take place via the elastic scattering of phonons with, for instance interface roughness and alloy fluctuations, hence the drift of hot phonons can be neglected. If the momentum relaxation of phonons is faster than their decay time, the change in the electron momentum between the emission and re-absorption of hot phonons can be quite large. Hence the production of hot phonons, with a finite lifetime may also enhance the momentum relaxation rate. The electron drift velocity at high fields is therefore reduced and consequently, inter-valley and real-space transfer negative differential resistance may be quenched.

In dilute nitrides the almost inevitable presence of nitrogen clusters, impurities, interface imperfections and dislocations will provide ample sources for phonon momentum scattering. The population of non-equilibrium phonons is therefore expected to be strongly non-drifting, particularly in the region where hot phonon effects are important. Therefore, the reduction in the high-fields drift velocity saturation is expected and the negative differential resistance may be inhibited.The aim of the work at Essex is to explore whether the observed electron drift velocity at high fields can be explained by invoking a mechanism involving the production of non-drifting hot phonons.

 

5. Hot electron transport devices based on wide band gap materials (GaN/ GaInN/AlN)

The large bandgaps of GaNand AlN make these materials promising as the ingredients of high-power electronic devices. The general aim is to make devices that can produce microwave power of the order of 100 W at X-band (8-12 GHz). High power entails a high electron concentrations and densities over 1.0 1013 cm-2 which, in AlGaN/GaN heterostructures are routinely observed in Hall measurements. Such densities are achieved as a direct consequence of the large spontaneous and strain-induced polarization in the AlGaN barrier. Thus, there is no need to add donors, unlike the case in GaAs-based structures. This independence on impurity concentration is a consequence of the symmetry property of wurtzite, which allows spontaneous polarization to occur, and its piezoelectricity and of the strong polarity of GaN and its alloys with Al. Electron transport under these conditions has the novel possibility of taking place in the absence of impurity scattering while at the same time involving a high density of electrons, which is a unique situation in semiconductor physics. It has been shown recently that when impurity scattering can be neglected and when scattering is dominated by acoustic phonons, then instabilities, electron cooling and squeezed electron states may be observed.

At the present time device performance is hampered by the low crystalline quality of MBE and MOCVD material, consequent on the lack of lattice-matched substrates. In spite of the effect of dislocations at densities exceeding 109 cm-2 and the effect of background impurity densities of order of 1018 cm-3, room-temperature Hall mobilities of electrons in the quasi-2D channel of an FET are frequently within 25% of the phonon-limited value of about 2000 cm2/Vs. In contrast, mobilities in bulk GaN are much lower.

                                                     (a)                                                                                    (b)

Figure 1. (a) Power Loss per electron versus electron temperature. (b) Electron drift velocity versus applied electric field at T=77K


Hot-electron transport in AlGaN/GaN heterostructures provides invaluable information on scattering mechanisms at high fields relevant to FET devices. The conduction-band structure of GaN, like GaAs, is suitable for the electron-transfer effect and associated negative differential resistance (NDR) at high electric fields, and there are several reports describing the velocity-field curve in bulk material predicted by Monte Carlo simulation

Another aspect of the large bandgap of GaN is the capability of that material to withstand very high fields (>1 MV/cm) before breaking down. Ridley and co workers recently calculated the conduction-band structure of GaN in its wurtzite and in its zinc blende forms using updated experimental input to the empirical pseudopotential model. On this basis they determined the probability of an electron avoiding a scattering event involving the emission or absorption of an optical phonon as it is accelerated through the lowest conduction band in a high electric field. The lowest scattering rate in wurtzite is along the G-A direction (1x1014 s-1 and energy independent) and with the field along this direction negative-mass effects become important at fields above 1.5 MV/cm and only a small chance of Bloch oscillations. The breakdown field is about 4 MV/cm; there is therefore a range of fields between 1 MV/cm and 4 MV/cm where interestingly new hot-electron effects can be expected [15, 16, 17].

At Essex we study scattering mechanisms limiting the electron drift hence the speed of high power FETs using polar and non-polar devices grown on sapphire or silicon carbide substrates and on free-standing substrates. We also investigate transport in very short devices and demonstrate electrical instabilities associated with intervalley transfer and negative mass NDR.
 

6. Hellish Devices

Hot electron light emitting and lasing in semiconductor heterostructure (HELLISH) devices are surface emitters based on longitudinal transport. It is a novel hot electron surface emitter consisting of a GaAs quantum well (QW) on the n- side of a Ga1-xAlxAs p-n junction. This has been currently adapted to GaAs/GaInNAs material structure for 1.3-1.6 μm communication window. These structures utilize hot electron transport parallel to the junction plane in high applied electric fields. The injection of hot electron-hole pairs into the QW is achieved via tunnelling and thermionic emission processes. However, at low applied electric fields, the carrier transport mechanism would be appropriately interpreted using "quasi flat band condition". These devices are able to emit via the top surface, and therefore, 2D arrays of light emitters, monolithic fabrication and integration can be achieved easily and cheaply. The HELLISH contacts arrangement is very simple. To make contact with the active layers, Au-Ge-Ni contacts are directly evaporated onto the n-layer and subsequently diffused through the active layers. External bias of either polarity is applied in the pulsed or cw mode between contacts of a simple bar shaped device.

The current line of this work is to adapt the semiconductor saturable absorber mirror (SESAM) integrated to the VCSEL-HELLISH where the active layers will be placed with GaInNAs material to match the optical communication windows. This integration will be expected to produce cost effective high frequency mode-locked pulse trains for the use of optical clock.

                                                            Ultra bright -HELLISH, its contacts and biasing arrangements.

HELLISH devices are hot electron surface emitters. Several types of light emitters have been demonstrated including HELLISH-1, HELLISH-2, Ultra-Bright HELLISH and HELLISH-VCSEL [All HELLISH devices utilise longitudinal transport, and hence, electrical fields are applied parallel to the layers which cause the carriers to heat in their respective channels. Therefore, hot carrier effects, thermionic emission, hot carrier tunnelling, and RST are the physical concepts behind the operation at the devices.

UB-HELLISH is a super radiant structure grown by MOVPE with addition of a bottom DBR. The DBR provides over 99% reflectivity so that emission previously lost from the substrate is reflected back through the device. The GaAs-air interface has a reflectivity of approximately R = [(3.6- 1)/(3.6+1)]2 ~ 30%, due to the discontinuities in the refractive index, and forms a partial or "quasi-cavity". Therefore it is able to operate as a super radiant structure, so called UB-HELLISH.

HIGH FIELD OPERATION

The 3D energy band profiles of HELLISH devices in thermal equilibrium condition. The top and bottom bands are the conduction and valence bands, respectively. Also shows the position of Fermi level and the reference level.

HELLISH devices simply consist of two diffused-in contacts which are separated by in a length (l). In thermal equilibrium, the band profile is uniformly formed along l. By placing both contacts on the top surface and diffusing through all layers, it is possible to apply longitudinal electric fields and enable mobile carriers to flow in both n- and p-channels. When the fields are on, energy bands tilt up according to the polarity of the applied voltage. The sequence of illustrations in figure below shows how the bands are being tilted by the longitudinal electric fields. As the applied voltage increases, the degree of tilting of the band increases proportionally as a result of stronger electric fields. However, the built-in field in the growth direction is not affected by the application of the longitudinal bias.

A sequence of pictures shows how the energy bands of HELLISH are tilted by longitudinal electric fields.

High electric field carrier dynamics of HELLISH devices have also been developed. Briefly, it involves electric field induction heating of mobile carriers, i.e., hot electrons and holes, in their respective channels. Hot electrons are injected into the quantum well via tunneling and thermionic emission. The well acts as a giant trap for the hot electrons diffusing or drifting into the depletion region.

The HELLISH-1 energy band profile with the QW on the n-side of the depletion region of AlxGa1-xAs p-n junction. En,p are the electric fields applied parallel to the layers. The injection of non-equilibrium carriers from the 3D AlxGa1-xAs layer into the first sub-band of the GaAs QW is via Ith (thermionic) and Itu (tunnelling) currents. Ideand Idh are the electron and hole drift currents in the QW, respectively. Ihis the hot hole injection into the well.

LOW FIELD OPERATION: QUASI FLAT-BAND CONDITION

One of the most important features of HELLISH device is the bidirectionality in terms of the polarity of the applied voltage. The emission region can be changed if the polarity of the applied voltage is reversed. Therefore, it displays optical XOR logic functions by its bidirectional property.


Illustration of bidirectionality of HELLISH devices with different biasing polarities. Left: the device is positively biased and light emission is from the left. Right: the device is negatively biased and light emission is from the right.

Infrared photographs, illustrating the growing emission region of a 1 mm UB-HELLISH device (the schematic is shown on top of the photos) with increasing fields. G = Ground. (a) positive polarity and (b) negative polarity.

VCSEL-HELLISH

The VCSEL consists of a HELLISH-1 cavity surrounded by upper and lower DBRs. The lower DBR provides a reflectivity in excess of 99%, while the reflectivity of the upper DBR is slightly lower to allow an output from the top surface. The QW is centralized within the cavity so that it is aligned to the anti-node of the confined optical field, and therefore, maximises gain with each round trip. The reflectivity and EL spectra of VCSEL-HELLISH are shown in figures below.

         

The reflectivityand EL spectrra of VCSEL-HELLISH.

TOP-HAT HELLISH (THH) WAVELENGTH CONVERTER

Unlike the standard HELLISH devices, the THH device is fabricated to a shorter n-channel than p-channel by etching. Ohmic contacts to the two channels are formed using Au-Zn and Au-Ni-Ge systems for the p-type and n-type contacts, respectively. Under normal operation, the device is biased with ±V at contacts 1 and 2, while contacts 3 and 4 are grounded. When the device is biased with the positive polarity the potential near to contact 2 (l2) is higher in the n-channel than the p-channel (Vn>Vp). This results in an effective reverse biased region, which acts as a light absorber. In contrast, the area near to contact 3 (l3) is effectively forward biased by the field, and therefore, can act as an emission region. In other words, owing to the shorter n-channel length, the applied electric field in the n-channel is higher than that in the p-channel, since both channels are equally biased. Because of the different electric field strengths within these channels, the energy band profile of the device is altered. The built-in potential barrier of the p-n junction is enhanced near the anode (drain) and flattened near the cathode (source). The reverse and forward biased regions of the THS can be interchanged simply by changing the applied field polarity It can, therefore, operate as a bi-directional field effect light emitter/detector. Another potential application would be the self-pulsation device, since it consists of both emission and absorption regions. The THH has been demonstrated as an all-optical wavelength converter (down conversion), using the set-up below

(a) Schematic of the THS device; (b) Illustration of the potential distributions along the n- (broken line) and p- (solid line) channels of the device. In the region Vn>Vp, the device is effectively reverse biased; and in the region Vp>Vn, it is effectively forward biased.

Illustration of THH as a multiple-wavelength converter.

Reflected spectra of the THH operating as a wavelength converter. The 850 nm light is modulated with the 647 nm incoming signal. Applied voltage Va = 6.5 V, 647 nm laser power =70 mW.

VCSOA HELLISH

Semiconductor optical amplifiers (SOAs) have become an important component of optical fiber networks in recent years. Many of the early SOA devices were based on Fabry Perot cavity lasers, since then a number of advanced structures, such as the traveling-wave amplifier (TWA), have been demonstrated leading to improved performance. Similarly, vertical cavity SOAs (VCSOAs), which have attracted considerable interest in recent years, have been demonstrated, and offer a number of potential advantages over conventional in-plane edge-emitting SOA devices. Main advantages are lower cost, inherent polarization insensitivity, higher fiber coupling efficiency, lower noise figure and potential for integration into high-density two-dimensional array architectures. So far, only a limited number of VCSOAs have been reported in the literature. These include both optically and electrically pumped devices operating at 1550 nm as well as an optically pumped 1300 nm device. Each of these devices has a structure similar to that of standard VCSELs. The bottom mirrors of these devices are produced to have reflectivities close to unity; this is achieved using many period of DBR stacks. In contrast, the top mirrors have relatively a few DBR periods. The lower reflectivity of the top mirror can provide enhanced absorption of pump power (optically) in quantum wells, as well as maximizing the gain-bandwidth production of the VCSOA. The low reflectivity of the top DBR designed for operation in reflection mode requires multiple quantum wells in the active region to give high single pass gain.

We have previously demonstrated several novel longitudinal transport surface-emitting HELLISH devices. In this work, we used THS for the VCSOA wafer with a short n-channel and a longer p-channel. The THS allows different fields to be applied across the n- and p-channels. Because of these different electric field strengths in the channels, the energy band profile of the THH device can be twisted resulting in an emission region and an absorption region within the same junction plane. It has, therefore, the essential elements required to construct a compact wavelength converter, which has been demonstrated at wavelength of 850 nm and 1.3 m m. The most interesting potential application of the THH-VCSOA is a single device which acts as a combined wavelength converter and optical amplifier.